The tautomerism of β-keto esters is a typical system of enol-keto tautomerism, which has been thoroughly studied in liquid phase, yet less in gas phase, for lacking of effective techniques. β-二酮类化合物存在着互变异构现象,是典型的烯醇-酮互变体系。其溶液体系的互变现象研究得比较透彻,而气相体系由于缺少研究手段,这方面的报道很少。